Self‐Organization of Oligomeric Helical Stacks Controlled by Substrate Binding in a Tobacco Mosaic Virus Like Self‐Assembly Process
Identifieur interne : 000330 ( Main/Exploration ); précédent : 000329; suivant : 000331Self‐Organization of Oligomeric Helical Stacks Controlled by Substrate Binding in a Tobacco Mosaic Virus Like Self‐Assembly Process
Auteurs : Anne Petitjean [États-Unis] ; Hélène Nierengarten [France] ; Alain Van Dorsselaer [France] ; Jean-Marie Lehn [France]Source :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 2004-07-12.
English descriptors
Abstract
Self‐assembly with a twist: Linear polyammonium threads are templates in the organization of helical heterocyclic building blocks to form stacks of helices as a model for the Tobacco Mosaic Virus. The length of the cationic substrate and the spacing of the positive charges within the thread dictate the size of the final self‐organized supramolecular architecture (see picture).
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DOI: 10.1002/anie.200353492
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